Thanks LI Mike, I will try to answer your questions.
2-Canada's Parliament/Peace Tower-Ottawa's most famous buildings?
Definitely
7-Government building-what is it?
That's the Langevin Block, where the office of the PM is located. Basically the executive branch of the government is there.
14-Is this Hull,Quebec?
Yes, I'm not sure what the white buildings is though.
15-Nice Fall country air view...where?
The view is from one of the lookouts at Gatineau Park in Quebec
16-I remember Ottawa had a Downtown pedestrian mall on which street?
Sparks Street
19-Hull Buildings-Government?
Of course it's the government
The complex is called Les Terasses de la Chaudiere
21-Interesting OC Transpo ad with a little humor for good measure...
Enouraging people to rat out their fellow citizens lol
25-Hull Skyline?
Yep, showing mostly the Place du Portage complex
26-Down on the Ottawa River?
Looking east towards Ottawa from the ferry
27-Ferry-where?
About 45 minutes west of Ottawa across from the Quebec town of Quyon
35,36-Downtown Ottawa-where?
West part of downtown, looking east down Lauier and Queen Streets respectively
44-Neat visitors center-where?
Directly across Wellington St from the Parliament buildings.
45-Lion sleeping on the job?
Nobody gives the post office any respect these days...
47-Slow down-where was this?
Sandy Hill, I think . I see these all over where kids are playing street hockey.
48-Canal?
Yes, as it enters/exits the Ottawa River.
51-Neat color in this air view-where?
From a lookout in Gatineau Park, looking SW to the Ottawa River
52-What is this building?
Gatineau City Hall
55-Interesting air view... 59-Hills-where?
Those are the Gatineau Hills north of Hull. View is from 24th floor of Portage I
65-Hull construction...
Ottawa actually. There is a huge empty area west of downtown known as LeBreton Flats.
68-Rideau Canal?
Right at the entrance between Chateau Laurier and Parliament Hill.
70-A perfect finish-no jumping the shark here! (Quebec side?)
Yes, driving along the river on the Quebec side west of the city.